Synthesis, structure und thermochemical reactivity of bismuth methoxide, BiOOCH3

Autor:	Felix Reifler, R.A. Gubser, Armin Reller, H.R. Oswald, Christian Baerlocher
Rok vydání:	1996
Předmět:	Rietveld refinement Inorganic chemistry Oxide chemistry.chemical_element General Chemistry Methoxide Condensed Matter Physics Bismuth chemistry.chemical_compound chemistry Sodium hydroxide Alkoxide General Materials Science Reactivity (chemistry) Methanol
Zdroj:	Solid State Ionics. 84:283-291
ISSN:	0167-2738
DOI:	10.1016/0167-2738(96)00081-1
Popis:	Microcrystalline bismuth methoxide, BiOOCH3, was synthesized by reacting bismuth nitrate pentahydrate in a sodium hydroxide/methanol mixture. The structure was determined with a Rietveld refinement in space group P4/nmm (a = 3.740 A , c = 10.513 A ) from X-ray powder data. The thermochemical reactivity is discussed with respect to its dependence of the gas atmosphere and the morphology as well as with respect to the formation of bismuth oxide exhibiting tailor-made textures and morphologies. The significance of the title compound as potential precursor compound for the generation of ternary or polynary oxides is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ae227664181cff4523df10a29652ee92 https://doi.org/10.1016/0167-2738(96)00081-1 Zobrazit plný text záznamu Full Text from ScienceDirect