Total Synthesis of seco-Lateriflorone
| Autor: | Sun Hee Kim, Emmanuel A. Theodorakis, Chinmay Chowdhury, Eric J. Tisdale, Binh G. Vong, Hongmei Li |
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| Rok vydání: | 2003 |
| Předmět: | |
| Zdroj: | ChemInform. 34 |
| ISSN: | 1522-2667 0931-7597 |
| DOI: | 10.1002/chin.200351207 |
| Popis: | A convergent strategy toward the synthesis of lateriflorone ( 5 ) is described. Our approach is based on biosynthetic considerations and draws on a sequence of prenylation, oxygenation and Claisen reactions for the construction of chromenequinone 6 , and a tandem Claisen/Diels–Alder reaction cascade for the synthesis of caged tricycle 7 . Union of fragments 6 and 7 led to the synthesis of seco-lateriflorone ( 49 ). |
| Databáze: | OpenAIRE |
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