Iridium-catalyzed ortho-C-H borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron
| Autor: | Tatsunosuke Amou, Ikuo Sasaki, Hajime Ito, Tatsuo Ishiyama |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
chemistry.chemical_classification
Boron Compounds Aldimine Aniline Compounds Molecular Structure Pentafluoroaniline Organic Chemistry chemistry.chemical_element Regioselectivity Iridium Biochemistry Borylation Medicinal chemistry Boronic Acids Catalysis chemistry Yield (chemistry) Organometallic Compounds Organic chemistry Imines Physical and Theoretical Chemistry |
| Zdroj: | Organicbiomolecular chemistry. 12(13) |
| ISSN: | 1477-0539 |
| Popis: | The development of an Ir-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline is reported. This reaction proceeded at 120 °C to afford the corresponding borylated products in high yield with good regioselectivity using an Ir complex formed in situ from [Ir(OMe)(cod)]2/2(C6F5)3P in the presence of 2-norbornene. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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