Asymmetric aerobic oxidation of secondary alcohols catalyzed by poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters modified with cyclodextrin derivatives
| Autor: | Shinjiro Takano, Tatsuya Tsukuda, Koto Hirano |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
010405 organic chemistry
Chemistry Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Cyclodextrin Derivatives Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Kinetic resolution chemistry.chemical_compound Polymer chemistry Materials Chemistry Ceramics and Composites Surface modification 2-Pyrrolidone |
| Zdroj: | Chemical communications (Cambridge, England). 55(100) |
| ISSN: | 1364-548X |
| Popis: | Surface modification of poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters (1.8 ± 0.6 nm) with aminated cyclodextrins induced aerobic oxidative kinetic resolution of racemic secondary alcohols (krel = 1.2). |
| Databáze: | OpenAIRE |
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