Precision Synthesis of Various Low‐Bandgap Donor–Acceptor Alternating Conjugated Polymers via Living Suzuki–Miyaura Catalyst‐Transfer Polymerization

Autor: Hwangseok Kim, Jaeho Lee, Taehyun Kim, Minyoung Cho, Tae‐Lim Choi
Rok vydání: 2022
Předmět:
Zdroj: Angewandte Chemie International Edition. 61
ISSN: 1521-3773
1433-7851
Popis: Herein, we demonstrate that living Suzuki-Miyaura catalyst-transfer polymerization (SCTP) using a RuPhos Pd G3 precatalyst is a versatile method for the precision synthesis of various donor-acceptor alternating conjugated polymers (DA ACPs). First, the living SCTP of biaryl monomers with combinations of both medium to strong A and D were optimized to produce DA ACPs with controlled number average molecular weight (M
Databáze: OpenAIRE
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