Effect of carbon nanotube (CNT) functionalization in epoxy-CNT composites
Autor: | Sagar Roy, Somenath Mitra, Roumiana S. Petrova |
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Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: |
Technology
Materials science Physical and theoretical chemistry QD450-801 Energy Engineering and Power Technology Medicine (miscellaneous) 02 engineering and technology Carbon nanotube TP1-1185 010402 general chemistry 01 natural sciences Article physical properties law.invention Nanomaterials Biomaterials functionalized carbon nanotube chemistry.chemical_compound law nanocomposites Composite material chemistry.chemical_classification Nanocomposite Process Chemistry and Technology Chemical technology thermal properties Epoxy Polymer 021001 nanoscience & nanotechnology 0104 chemical sciences Surfaces Coatings and Films chemistry Triethylenetetramine visual_art visual_art.visual_art_medium Surface modification 0210 nano-technology Glass transition interfacial interaction Biotechnology |
Zdroj: | Nanotechnology Reviews, Vol 7, Iss 6, Pp 475-485 (2018) |
ISSN: | 2191-9097 2191-9089 |
Popis: | The effect of carbon nanotube (CNT) functionalization in altering the properties of epoxy-CNT composites is presented. The presence of functional groups effectively influenced the colloidal behavior of CNTs in the precursor epoxy resin and the hardener triethylenetetramine (TETA), which affected the synthesis process and eventually the interfacial interactions between the polymer matrix and the CNTs. The physical, thermal, and electrical properties of the composites exhibited strong dependence on the nature of functionalization. At a 0.5-wt% CNT loading, the enhancement in tensile strength was found to be 7.2%, 11.2%, 11.4%, and 14.2% for raw CNTs, carboxylated CNTs, octadecyl amide-functionalized CNTs, and hydroxylated CNTs, respectively. Glass transition temperatures (T g) also varied with the functionalization, and composites prepared using hydroxylated CNTs showed the maximum enhancement of 34%. |
Databáze: | OpenAIRE |
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