Fractional Quantization of Molecular Pseudorotation inNa3

Autor:	Edward R. Grant, Josef W. Zwanziger, Guy Delacrétaz, Ludger Wöste, Robert L. Whetten
Rok vydání:	1986
Předmět:	chemistry.chemical_classification Physics Quantization (physics) chemistry Quantum mechanics Triatomic molecule Jahn–Teller effect General Physics and Astronomy Level structure Pseudorotation Adiabatic process Inorganic compound Molecular beam
Zdroj:	Physical Review Letters. 56:2598-2601
ISSN:	0031-9007
DOI:	10.1103/physrevlett.56.2598
Popis:	Fractional quantization of the adiabatic pseudorotation in an isolated molecule is reported. This result, concerning the large-amplitude pseudorotation in ${2}^{2}{E}^{\ensuremath{'}}{\mathrm{Na}}_{3}$, constitutes the first direct verification of the adiabatic sign-change theorem, and also presents the most complete picture of the level structure and internuclear dynamics of a metal-atom cluster yet given.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ad62275570f36c31948acc736fc93f92 https://doi.org/10.1103/physrevlett.56.2598 Zobrazit plný text záznamu