Rare-earth-metal half-sandwich complexes incorporating methyl, methylidene, and hydrido ligands

Autor: Dennis A. Buschmann, Lion Schumacher, Reiner Anwander
Rok vydání: 2022
Předmět:
Zdroj: Chemical Communications. 58:9132-9135
ISSN: 1364-548X
1359-7345
DOI: 10.1039/d2cc03532d
Popis: [Cp*Ln(μ2-Me)2]3 slowly converts into Cp*3Y3(μ2-Me)3(μ3-CH2)(μ3-H)(thf)3 showing selective reactivity towards ketones and full consumption of all bridging ligands with methanol.
Databáze: OpenAIRE