Salicylaldimines: Formation via Ring Contraction and Synthesis of Mono- and Heterobimetallic Alkali Metal Heterocubanes

Autor: Laura Wolz, Crispin Lichtenberg, Krzysztof Radacki, Anna Hanft, Malte Jürgensen
Rok vydání: 2020
Předmět:
Zdroj: Inorganic chemistry. 59(23)
ISSN: 1520-510X
Popis: The formation of salicylaldimine derivatives via ring contraction as byproducts in 2-aminotropone syntheses has been investigated. Salicylaldiminate (SAI) complexes of the alkali metals Li-K have been synthesized and transformed into heterobimetallic complexes. Important findings include an unusual double heterocubane structure of the homometallic sodium SAI, an unprecedented ligand-induced
Databáze: OpenAIRE