Two Separable Conformers of TATP and Analogues Exist at Room Temperature

Autor:	Gottlieb L, Denekamp C, Tsoglin A, Shilav R, Kapon M, Tamiri T
Rok vydání:	2005
Předmět:	Crystallography Chemistry Organic Chemistry Organic systems Analytical chemistry Crystal structure Physical and Theoretical Chemistry Biochemistry Conformational isomerism Separable space
Zdroj:	Organic Letters. 7:2461-2464
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol050801c
Popis:	[reaction: see text] TATP gives rise to two separable conformations because the barrier for interconversion between them is relatively high at room temperature. This kind of behavior is rare in cyclic organic systems and is the result of poor overlap in the "flip-flop" transition state. The crystal structure of the analogous tricyclohexanone triperoxide also indicates the presence of two conformers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::acc8e4a58143c1d5e1382de814abd414 https://doi.org/10.1021/ol050801c Zobrazit plný text záznamu