Mass spectrometric detection of enantioselectivity in three-component complexation, copper(ii)-chiral tetradentate ligand-free amino acid in solution
| Autor: | Hiroshi Tsukube, Motohiro Shizuma, Hideya Kawasaki, Ryuichi Arakawa, Hiroyuki Miyake, Hirofumi Sato, Satoshi Shinoda, Daisuke Ono, Takashi Nakakoji |
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| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
Ligand Chemistry Component (thermodynamics) Electrospray ionization Metals and Alloys Enantioselective synthesis chemistry.chemical_element General Chemistry Free amino Combinatorial chemistry Copper Mass spectrometric Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Materials Chemistry Ceramics and Composites Tetradentate ligand |
| Zdroj: | Chemical communications (Cambridge, England). 56(1) |
| ISSN: | 1364-548X |
| Popis: | By using electrospray ionization mass spectrometry coupled with the use of deuterium-labelled quasienantiomers, enantioselective coordination of a free amino acid as the second ligand of a copper(II) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time. |
| Databáze: | OpenAIRE |
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