Stereochemistry of base-catalyzed double-bond migration in allyl ethers

Autor:	J. A. A. van Drunen, H. Kloosterziel
Přispěvatelé:	Chemical Engineering and Chemistry
Jazyk:	angličtina
Rok vydání:	1970
Předmět:	chemistry.chemical_classification NMR spectra database Double bond chemistry Base (chemistry) Stereochemistry General Chemistry Isomerization Catalysis Ion
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas, 89(1), 32-36. Royal Netherlands Chemical Society
ISSN:	0165-0513
DOI:	10.1002/recl.19700890106
Popis:	Base-catalyzed isomerization of trans-3-methoxy-1-phenylpropene yields stereospecifically as the initial product cis-1-methoxy-3-phenylpropene. This is caused by the (intermediate) formation of the cis-1-methoxy-trans-3-phenylallyl anion (I), which is energetically favored over the trans-isomeric anion (II). The NMR spectra of I and II are described. [on SciFinder (R)]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ac594d8e4b205a895b8e6a77b84c747f https://doi.org/10.1002/recl.19700890106 Zobrazit plný text záznamu Plný text