Characteristic infrared frequencies of rotational isomers of alkyl chlorides

Autor:	J. J. Shipman, V. L. Folt, Samuel Krimm
Rok vydání:	1962
Předmět:	chemistry.chemical_classification Crystallography Carbon atom chemistry Stereochemistry Infrared Atom General Earth and Planetary Sciences Infrared spectroscopy Hydrogen atom Alkyl General Environmental Science
Zdroj:	Spectrochimica Acta. 18:1603-1613
ISSN:	0371-1951
DOI:	10.1016/0371-1951(62)80024-1
Popis:	A study of the infrared spectra of primary, secondary and tertiary alkyl chlorides reveals that the frequency of the so-called C-Cl stretching mode is a function of the detailed structure in the vicinity of the C-Cl bond. In primary chlorides the frequency region depends on whether a hydrogen atom or a carbon atom is trans to the Cl atom across the common C-C bond. In secondary chlorides it is found that the trans substituents on both C-C bonds adjacent to the C-Cl bond are important in determining the frequency region, and a similar result is observed for the tertiary chlorides. Frequency ranges for the various rotationally isomeric structures of primary, secondary and tertiary chlorides are given.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ac2c58b93d0587c0df303412b83c927f https://doi.org/10.1016/0371-1951(62)80024-1 Zobrazit plný text záznamu