Preparation of 2,5,7-Trithiabicyclo[2.2.1]heptane from 1,2-Bis-triisopropylsilanylsulfanyl Alkenes

Autor:	Helene Juteau, Yves Gareau, Richard G. Ball, Nancy N. Tsou
Rok vydání:	2005
Předmět:	Heptane Bicyclic molecule Organic Chemistry General Medicine Biochemistry Medicinal chemistry Adduct Crystal chemistry.chemical_compound chemistry Yield (chemistry) Organic chemistry Lewis acids and bases Physical and Theoretical Chemistry
Zdroj:	Organic Letters. 8:59-61
ISSN:	1523-7052 1523-7060
Popis:	[reaction: see text] The chemical behavior of 1,2-bis-triisopropylsilanylsulfanyl alkenes 1 is relatively unexplored, and the weak sulfur-silicon bonds give rise to various transformations. Under acidic conditions (HCl) and in the presence of a Lewis acid at room temperature the bicyclic adduct 2 is obtained in good yield. The structure was confirmed by X-ray crystal analysis with R = benzyl.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ab94fb7bad470db153c3c0952515ce58 https://doi.org/10.1021/ol0524858 Zobrazit plný text záznamu