Synthesis and characterization of coordination polymers prepared from CuII and NiII cyclam perchlorate and carmosine
| Autor: | Mihaela Vlassa, George Borodi, Cristian Silvestru, Gabriela Blăniţă, Mircea Vlassa, Ileana Cojocaru |
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| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Chemistry Coordination polymer Inorganic chemistry Salt (chemistry) cyclam self-assembly General Chemistry Polymer coordination polymer Perchlorate chemistry.chemical_compound symbols.namesake Polymer chemistry Cyclam azo dye Materials Chemistry symbols Self-assembly Raman spectroscopy QD1-999 |
| Zdroj: | Open Chemistry, Vol 9, Iss 2, Pp 224-231 (2011) |
| ISSN: | 2391-5420 |
| DOI: | 10.2478/s11532-010-0141-9 |
| Popis: | Reaction of [CuII(cyclam)](ClO4)2 or [NiII(cyclam)](ClO4)2 in DMF with aqueous 4-hydroxy-3-(4-sulfonato-1-naphthylazo)naphthalen-1-sulfonate disodium salt (carmoisine) yielded coordination polymers {[CuII(cyclam)](carmoisine dianion)(H2O)5}n and powder {[NiII(cyclam)](carmoisine dianion)}n, respectively (cyclam = 1,4,8,11-tetrazacyclotetradecane). They were characterized by powder X-ray diffraction, IR, Raman spectrometry and TGA. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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