A new, highly selective, free-radical aerobic oxidation of silanes to silanols catalysed by N-hydroxyphthalimide under mild conditions

Autor:	F. Recupero, Chiara Guidarini, Francesca Fontana, Gian Franco Pedulli, Francesco Minisci, Carlo Punta
Rok vydání:	2002
Předmět:	Silanes Organic Chemistry Settore CHIM/07 - Fondamenti Chimici delle Tecnologie chemistry.chemical_element Free radicals N-hydroxyphthalimide Silanols Oxygen Redox Catalysis chemistry.chemical_compound chemistry Chain (algebraic topology) Polymer chemistry Chain reactions Selectivity Chain reaction
Zdroj:	Scopus-Elsevier
Popis:	Silanes are oxidised to silanols by molecular oxygen, under N-hydroxyphthalimide and Co(II) catalysis, under very mild conditions and in good yields and selectivity. The reaction proceeds through the superimposition of a redox chain to a free-radical chain reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aa45438e69fa3885503ce7cba067555a http://hdl.handle.net/11311/240222 Zobrazit plný text záznamu