Copper ions-assisted inorganic dynamic porogen of graphene-like multiscale microporous carbon nanosheets for effective carbon dioxide capture
| Autor: | Suisui Su, Baocheng Yang, Weiwei Shi, Binbin Chang, Shiji Liu, Quanqi Zhang |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Graphene chemistry.chemical_element 02 engineering and technology Microporous material 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Copper 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Biomaterials chemistry.chemical_compound Colloid and Surface Chemistry Adsorption chemistry Chemical engineering law Carbon dioxide 0210 nano-technology Selectivity Carbon Pyrolysis |
| Zdroj: | Journal of colloid and interface science. 600 |
| ISSN: | 1095-7103 |
| Popis: | The superior ultramicroporosity and enriched surface CO2-philic sites are simultaneously required features for high-efficiency carbon-based CO2 adsorbents. Unfortunately, these characteristics are usually incompatible and difficult to integrate into one porous carbon material. Herein, we report a new copper ions (Cu2+)-assisted dynamic porogen to construct hierarchically microporous carbon nanosheets in a large scale with high heterogeneity for solving such issue. Cu2+ can be equably dispersed in precursor by coordination interactions of COO-Cu and Cu-N, which can anchor more N/O-containing species in final product. The reduced cuprous ions (Cu+) in pyrolysis process functions as a dynamic porogen to tailor uniform ultramicropores. Importantly, copper salt extracted in this synthetic procedure allows cyclic utilization, realizing a green and low-cost process. The obtained carbon sheets possess a graphene-like morphology, a high surface area and a high-proportioned multiscale microporosity, especially a high-density ultramicropores of 0.4–0.7 nm and supermicroproes of 0.8–1.5 nm. The maximized synergistic effect of morphology, high density of multi-sized ultramicroporosity and surface high heterogeneity endow the resultant microporous carbon nanosheets with the remarkable CO2 capture property, including a high uptake, a moderate adsorption heat, a good selectivity and superior recyclability. |
| Databáze: | OpenAIRE |
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