Metal-Catalyzed Postpolymerization Strategies for Polar Group Incorporation into Polyolefins Containing C–C, C═C, and Aromatic Rings

Autor:	Gabriel Menendez Rodriguez, M. Mar Díaz-Requejo, Pedro J. Pérez
Rok vydání:	2021
Předmět:	Catalysts Polymers and Plastics Polymers Chemistry Organic Chemistry Aromaticity Catalysis Inorganic Chemistry Metal Group (periodic table) Hydrosilylation visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Polar Functionalization Materials
Zdroj:	Macromolecules. 54:4971-4985
ISSN:	1520-5835 0024-9297
DOI:	10.1021/acs.macromol.1c00374
Popis:	Polymeric materials bearing polar groups constitute a class of macromolecules with interest in a number of uses. Because the direct synthesis employing polymerization strategies from polar monomers is very often precluded by catalyst poisoning or uncontrolled side reactions, the alternative postpolymerization route consisting in modifying a previously prepared polymer is continuously progressing. However, such a posteriori modification depends on the existence of potential reaction sites in the polymer. Because of this, polyolefins are the most challenging substrates to work with and, among them, the saturated ones. In this contribution, the current state of the art of the metal-catalyzed modification of polyolefins and subsequent polar group incorporation is provided. We acknowledge financial support from the Ministerio de Ciencia e Innovacion (CTQ2017-82893-C2-1-R), Junta de Andalucia (P18-RT-1536), and Universidad de Huelva (P.O.Feder UHU-1260216 and UHU-1254043). DYNASOL SLU is also highly appreciated for financial support. Funding for open access charge: Universidad de Huelva / CBUA
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a9b5e4e9db312a5150fa15979b779a06 https://doi.org/10.1021/acs.macromol.1c00374 Zobrazit plný text záznamu