Luminescent complexes beyond the platinum group: the d10 avenue
| Autor: | Andrea Barbieri, Gianluca Accorsi, Nicola Armaroli |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: |
Materials science
Ligand Rare earth Metals and Alloys Nanotechnology General Chemistry Platinum group Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal LIGAND CHARGE-TRANSFER DENSITY-FUNCTIONAL THEORY LIGHT-EMITTING-DIODES CU-I COMPLEXES IRIDIUM CYCLOMETALATED COMPLEXES TRANSITION-METAL-COMPLEXES GOLD(I) THIOLATE COMPLEXES RAY CRYSTAL-STRUCTURES COORDINATION-COMPOUNDS PHOTOPHYSICAL PROPERTIES visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Luminescence |
| Zdroj: | Chemical communications (Lond., 1996, Print) (2008): 2185–2193. doi:10.1039/b716650h info:cnr-pdr/source/autori:A. Barbieri; G. Accorsi; N. Armaroli/titolo:Luminescent complexes beyond the platinum group: the d10 avenue/doi:10.1039%2Fb716650h/rivista:Chemical communications (Lond., 1996, Print)/anno:2008/pagina_da:2185/pagina_a:2193/intervallo_pagine:2185–2193/volume |
| DOI: | 10.1039/b716650h |
| Popis: | Luminescent metal complexes are key materials for several applications such as lighting, analytical probes, and lasers. In many cases compounds based on precious (i.e. platinum group) and rare earth metals are utilized, which are often rather expensive and environmentally problematic. In recent years, interest is growing in luminescent complexes based on less traditional but more abundant and cheaper metal elements. In this scenario compounds of metals with a d(10) electronic configuration are playing a prominent role, also thanks to the versatility of their luminescent levels which can be of ligand centred, charge transfer or, in the case of polynuclear compounds, even metal-centred nature. Here we focus on some selected examples of Cu(I), Ag(I), Au(I), Zn(II) and Cd(II) luminescent complexes to suggest some possible routes towards promising and unprecedented emitting materials. |
| Databáze: | OpenAIRE |
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