Intramolecular Didehydro-Diels-Alder Reaction for the Synthesis of Benzo- and Dihydrobenzo-Fused Heterocycles

Autor:	Kay M. Brummond, Justin T. Proto, Ashley E. Bober
Rok vydání:	2017
Předmět:	Reaction conditions 010405 organic chemistry Chemistry Organic Chemistry Substrate (chemistry) 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Intramolecular force Organic chemistry Physical and Theoretical Chemistry Selectivity Diels–Alder reaction
Zdroj:	Organic letters. 19(7)
ISSN:	1523-7052
Popis:	Using an intramolecular didehydro-Diels–Alder reaction, ene–yne substituted pyrroles, thiophenes, and furans afford functionalized indoles, benzothiophenes, and benzofurans and the corresponding dihydroaromatic products. Product selectivity for the aromatic or dihydroaromatic product is controlled by the reaction conditions, which vary depending upon the substrate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a9496b5a69db262d492301d0843a048c https://pubmed.ncbi.nlm.nih.gov/28267342 Zobrazit plný text záznamu