Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(ii) and manganese(ii)

Autor: Cynthia T. Brewer, Ray J. Butcher, Ann Marie Schmiedekamp, Greg Brewer, Carol Viragh, Luciann Cuenca, Everett E. Carpenter
Rok vydání: 2005
Předmět:
Zdroj: Dalton Transactions. :3617
ISSN: 1477-9234
1477-9226
DOI: 10.1039/b511566c
Popis: The iron(II) and manganese(II) complexes of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, approximately 2.44 è, metal to apical nitrogen bond.
Databáze: OpenAIRE