Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(ii) and manganese(ii)
Autor: | Cynthia T. Brewer, Ray J. Butcher, Ann Marie Schmiedekamp, Greg Brewer, Carol Viragh, Luciann Cuenca, Everett E. Carpenter |
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Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Dalton Transactions. :3617 |
ISSN: | 1477-9234 1477-9226 |
DOI: | 10.1039/b511566c |
Popis: | The iron(II) and manganese(II) complexes of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, approximately 2.44 è, metal to apical nitrogen bond. |
Databáze: | OpenAIRE |
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