Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]
| Autor: | M. M. Kubicki, Yoann Rousselin, Lydie Viau, Michael Knorr |
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| Přispěvatelé: | Univers, Transport, Interfaces, Nanostructures, Atmosphère et environnement, Molécules (UMR 6213) (UTINAM), Université de Franche-Comté (UFC), Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS), Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon] (ICMUB), Centre National de la Recherche Scientifique (CNRS)-Université de Bourgogne (UB)-Institut de Chimie du CNRS (INC) |
| Rok vydání: | 2021 |
| Předmět: |
crystal structure
Coordination polymer C—H⋯Br hydrogen bonding Crystal structure 010402 general chemistry 01 natural sciences Research Communications c—h...br hydrogen bonding Crystal chemistry.chemical_compound C—H...Br hydrogen bonding [CHIM.CRIS]Chemical Sciences/Cristallography Thiophene [CHIM.COOR]Chemical Sciences/Coordination chemistry General Materials Science SBus Crystallography biology 010405 organic chemistry Hydrogen bond General Chemistry Condensed Matter Physics biology.organism_classification 0104 chemical sciences 3. Good health [CHIM.POLY]Chemical Sciences/Polymers chemistry QD901-999 two-dimensional coordination polymer Tetra Cu2Br2 rhomboids tetrahydrothiophene tetrahydrothiophene Tetrahydrothiophene |
| Zdroj: | Acta crystallographica. Section E, Crystallographic communications Acta crystallographica. Section E, Crystallographic communications, International Union of Crystallography, 2021, 77 (7), pp.744-748. ⟨10.1107/S2056989021006460⟩ Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 7, Pp 744-748 (2021) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/s2056989021006460 |
| Popis: | Treatment of CuBr with tetrahydrothiophene produces a layered coordination polymer. The polymeric title compound, [Cu2Br2(C4H8S)2]n, CP1, represents an example of a two-dimensional coordination polymer resulting from reaction of CuBr with tetrahydrothiophene (THT) in MeCN solution. The two-dimensional layers consist of two different types of rhomboid-shaped dinuclear Cu(μ2-Br)2Cu secondary building units (SBUs); one with a quite loose Cu⋯Cu separation of 3.3348 (10) Å and a second one with a much closer intermetallic contact of 2.9044 (9) Å. These SBUs are interconnected through bridging THT ligands, in which the S atom acts as a four-electron donor bridging each Cu(μ2-Br)2Cu unit in a μ2-bonding mode. In the crystal, the layers are linked by very weak C—H⋯·Br hydrogen bonds with H⋯Br distances of 2.95 Å, thus giving rise to a three-dimensional supramolecular network. |
| Databáze: | OpenAIRE |
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