Intermolecular Hydroaminoalkylation of Propadiene

Autor:	Malte Fischer, Ruediger Beckhaus, René Zimmering, Sven Doye, Michael Warsitz, Tobias Kaper
Rok vydání:	2020
Předmět:	010405 organic chemistry Communication Organic Chemistry Intermolecular force amines chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis Communications C−H activation 0104 chemical sciences Allylamines | Hot Paper chemistry.chemical_compound chemistry allenes hydroaminoalkylation Polymer chemistry titanium Propadiene Titanium
Zdroj:	Chemistry (Weinheim an Der Bergstrasse, Germany)
ISSN:	1521-3765
Popis:	Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6‐bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium‐carbon bond of a titanaaziridine. Propadiene undergoes regioselective hydroaminoalkylation reactions with N‐aryl‐ and N‐alkyl‐substituted benzylamines in the presence of an aminopyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in very good yields (up to 97 %) and with regioselectivities as high as 99:1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a8b32c674f5ab1bca9403b960459ba5b https://pubmed.ncbi.nlm.nih.gov/32844473 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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