The influence of alkyl polyglucosides (and highly ethoxylated alcohol boosters) on the phase behavior of a water/toluene/technical alkyl polyethoxylate microemulsion system
Autor: | Dragan Zlatanovic, Snezana Nikolic-Mandic, Zoran Nedić, Aleksandar Lolić, Marija Ilić, Vesna Pavelkic, Franz-Hubert Haegel |
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Rok vydání: | 2016 |
Předmět: |
General Chemical Engineering
Inorganic chemistry Alcohol 02 engineering and technology 010402 general chemistry 01 natural sciences chemistry.chemical_compound alkyl polyglucoside Pulmonary surfactant Phase (matter) efficiency booster toluene Microemulsion lcsh:Chemical engineering lcsh:HD9650-9663 Alkyl Phase diagram chemistry.chemical_classification oxoalcohol ethoxylate fish diagrams lcsh:TP155-156 microemulsion 021001 nanoscience & nanotechnology Toluene 0104 chemical sciences chemistry Solubilization “fish” diagrams 0210 nano-technology lcsh:Chemical industries |
Zdroj: | Chemical Industry and Chemical Engineering Quarterly, Vol 22, Iss 1, Pp 27-32 (2016) Chemical Industry and Chemical Engineering Quarterly / CICEQ |
ISSN: | 2217-7434 1451-9372 |
DOI: | 10.2298/ciceq141105015i |
Popis: | The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering the extreme hydrophilic nature of the sugar headgroup. The addition of hydrophilic alcohol ethoxylate (C18E100) to the water/toluene/Lutensol ON 50 system increases the solubilization capacity of the surfactant, even if the co-surfactant is used in small quantities, and shifts the one-phase region to higher temperature by a few degrees Celsius. [Projekat Ministarstva nauke Republike Srbije, br. 172051] |
Databáze: | OpenAIRE |
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