Calix[4]pyrrolato gallate: square planar-coordinated gallium(iii) and its metal–ligand cooperative reactivity with CO2 and alcohols

Autor:	Lukas M. Sigmund, Eliane Engels, Nick Richert, Lutz Greb
Rok vydání:	2022
Předmět:	General Chemistry
Zdroj:	Chemical Science. 13:11215-11220
ISSN:	2041-6539 2041-6520
Popis:	Ideally square-planar coordinated gallium(iii) species is isolated and fully characterized. Spontaneous metal–ligand cooperative reactivity towards CO2 is observed, while OH-bond activation of alcohols can be triggered by protonation of the ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a8724bb18434fb71ba910440056af9e6 https://doi.org/10.1039/d2sc03054c Zobrazit plný text záznamu