Modular Ligands for Dirhodium Complexes Facilitate Catalyst Customization

Autor:	Dennis Gillingham, Antoinette Chougnet, Stefanie Geigle, Wolf-Dietrich Woggon, Daniel G. Bachmann, Pascal J. Schmidt
Rok vydání:	2015
Předmět:	Steric effects Modularity (networks) business.industry Chemistry Ligand Chemical biology chemistry.chemical_element General Chemistry Modular design Combinatorial chemistry 3. Good health Rhodium Catalysis Organic chemistry Stereoselectivity business
Zdroj:	Advanced Synthesis & Catalysis
ISSN:	1615-4150
Popis:	Although stereoselectivity is often the focus of ligand optimizations in catalysis, ligand modularity can be used to control many other properties of catalysts. For example, solubility, amenability to purification, and steric shielding of sensitive catalytic intermediates are all important, but seldom appreciated, functions of ligands. We describe a brief and modular approach to various homo- and heteroleptic lantern-type rhodium(II) complexes and perform benchmarking studies with the new catalysts in common rhodium(II)-catalyzed reactions. We demonstrate the power of ligand modularity by creating catalysts customized for aqueous catalysis or for applications in chemical biology.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a822d80c5df7bcdccccc8dd2d8528e6e https://doi.org/10.1002/adsc.201500050 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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