Red-shifted backbone N–H photocaging agents
Autor: | Taysir K. Bader, Zachary T. Ball, Hallie O. Trial, Mark D. Distefano, Mekedlawit T. Setegne, Reyner D. Vargas, Alicia E. Mangubat-Medina |
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Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Organic & Biomolecular Chemistry. 18:5110-5114 |
ISSN: | 1477-0539 1477-0520 |
DOI: | 10.1039/d0ob00923g |
Popis: | Light is a uniquely powerful tool for spatiotemporal control of molecular structure, necessitating the development of new photocaging approaches. This communication describes the design, synthesis, and reactivity of two new photoreactive boronic acid reagents for backbone N-H modification and subsequent photocleavage. |
Databáze: | OpenAIRE |
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