A double phosphabetaine formed from 1,3,5-triaza-7-phosphaadamantane (PTA) with acetylenedicarboxylic acid and its Ag(CF3SO3)-based coordination polymer

Autor: Éva Kováts, Ágnes Kathó, Ferenc Joó, Gyula Tamás Gál, Gábor Papp, Csenge Tamara Szolnoki, Henrietta Horváth, Antal Udvardy
Rok vydání: 2021
Předmět:
DOI: 10.6084/m9.figshare.17091327
Popis: The adduct of acetylenedicarboxylic acid and the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA, 1) in 1:2 molar ratio, was synthesized both in aqueous solution and under anhydrous conditions in a planetary ball mill (pbm). The resulting double phosphabetaine (2) was characterized by 1H-, 13C-, and 31P-NMR spectroscopy, ESI-mass spectroscopy, and elemental analysis, furthermore, its solid-state structure was determined by single crystal X-ray diffraction. SXRD also revealed that in aqueous solution 2 reacted with AgSO3CF3 to yield a 2 D polymer.
Databáze: OpenAIRE
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