Ultrasound-Assisted, Base-Catalyzed, Homogeneous Reaction for Ferulic Acid Production from γ-Oryzanol
| Autor: | Hung Phuoc Duong, Thao Thanh Xuan Le, Yasuaki Maeda, Long Duc Huynh, Kiyoshi Imamura, Anh Tuan Do, Hoa Thi Truong, Norimichi Takenaka, Manh Van Do, Linh Thi Nguyen |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Potassium hydroxide Base (chemistry) Article Subject business.industry Ultrasound 04 agricultural and veterinary sciences General Chemistry 040401 food science Catalysis lcsh:Chemistry Ferulic acid chemistry.chemical_compound Hydrolysis 0404 agricultural biotechnology lcsh:QD1-999 chemistry Yield (chemistry) Irradiation business Nuclear chemistry |
| Zdroj: | Journal of Chemistry, Vol 2018 (2018) |
| ISSN: | 2090-9063 |
| DOI: | 10.1155/2018/3132747 |
| Popis: | A method for producing ferulic acid by ultrasound-assisted, homogeneous, base-catalyzed hydrolysis of γ-oryzanol was developed. Experiments were conducted using various reaction temperatures and ratios of γ-oryzanol to base catalyst in both homogeneous and heterogeneous systems. The reaction performed without ultrasound under the homogeneous conditions of potassium hydroxide/γ-oryzanol ratio (wt/wt) 20 : 1 and 75°C gave a ferulic acid yield of 83.3% in 3 h. Acceleration of the homogeneous reaction using ultrasound irradiation at 20 (horn type) and 200 kHz (planar type) was explored by evaluating the kinetic parameters. At 30°C, the ratios of ultrasonic irradiation at low (20 kHz, 50 W) and high (200 kHz, 50 W) frequencies versus those of the heating method increased by 2.0- and 1.4-fold in comparison with those at 60°C, respectively. The contribution of ultrasonic irradiation (50 W) to the hydrolysis reaction decreased with increase of temperature. However, irradiation at 20 kHz and a power of 180 W gave a 94% ferulic acid yield at 60°C in 3 h. These results indicate that the use of low frequency (horn type and high-power irradiation) enabled yields higher than 90% to be obtained. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
| Nepřihlášeným uživatelům se plný text nezobrazuje | K zobrazení výsledku je třeba se přihlásit. |