Revealing the crystal phases of primary particles formed during the coprecipitation of iron oxides

Autor:	Yu Mao, Zuoheng Zhang, Hongfeng Zhan, Jianfei Sun, Yan Li, Zhenhuang Su, Yonghua Chen, Xingyu Gao, Xiao Huang, Ning Gu
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:5749-5752
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc01617f
Popis:	The mechanistic investigation of the coprecipitation formation of iron oxides has been a long-standing challenge due to the rapid reaction kinetics and high complexity of iron hydrolysis reactions. Although a few studies have suggested that the coprecipitation of iron oxide nanoparticles follows a non-classic route through inter-particle attachment, the compositions of the primary particles remain undetermined. Herein, by using a specially designed gas/liquid mixed phase fluidic reactor we controlled the reaction time from 3 s to over 5 min, and successfully identified the concentration of different intermediate phases as a function of time. We suggest that the initial Fe
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7c4443ffb18a860a8d6795c27f6ad37 https://doi.org/10.1039/d2cc01617f Zobrazit plný text záznamu