Epioxyzoanthamine, a new zoanthamine-type alkaloid and the unusual deuterium exchange in this series

Autor:	Antonio Hernández Daranas, José J. Fernández, José A. Gavín, Manuel Norte
Přispěvatelé:	Ministerio de Educación y Ciencia (España)
Rok vydání:	1998
Předmět:	inorganic chemicals Stereochemistry Alkaloid Organic Chemistry Exchange Zoanthamine Deuterium Biochemistry Epioxyzoanthamine chemistry.chemical_compound Norzoanthamine chemistry Drug Discovery Hydrogen–deuterium exchange Zoanthamine alkaloids Methylene Spectral data After treatment
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(98)00423-2
Popis:	A new alkaloid, epioxyzoanthamine , has been isolated from a marine zoanthid. Its structure and relative stereochemistry were determined through the interpretation of NMR spectral data. This compound as well as norzoanthamine, showed an unusual deuterium exchange at the methylene C-11 after treatment with D2O. A new alkaloid, epioxyzoanthamine , (R1=CH2OH; R2=H) has been isolated from a marine zoanthid. Its structure and relative stereochemistry were determined through the interpretation of NMR spectral data. This compound as well as norzoanthamine, showed an unusual deuterium exchange at the methylene C-11 after treatment with D2O.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a76e2038fb27eb7478f6239f1f99c6f5 https://doi.org/10.1016/s0040-4020(98)00423-2 Zobrazit plný text záznamu Full Text from ScienceDirect