Stimuli-responsive metal-directed self-assembly of a ring-in-ring complex
| Autor: | José M. Quintela, Carlos Peinador, Marcos Garcia, Cristina Alvariño, Víctor Blanco, Carlos Platas-Iglesias |
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| Rok vydání: | 2016 |
| Předmět: |
Directed self assembly
Stimuli responsive 010405 organic chemistry Chemistry Ligand DOSY Host-guest Metallacycle 010402 general chemistry Ring (chemistry) Bioinformatics 01 natural sciences NMR 0104 chemical sciences Inorganic Chemistry Metal Crystallography visual_art visual_art.visual_art_medium Solvent polarity Palladium |
| Zdroj: | RUC. Repositorio da Universidade da Coruña instname |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c6dt01835a |
| Popis: | [Abstract] Concentration, temperature and/or solvent polarity control the speciation on the metal-directed self-assembly of a ditopic pyridyl ligand L with cis-protected Pd(II) metal centers. This results into a controllable dynamic system, involving a [Pd2L2]6+ metallacycle and a [Pd4L4]12+ ring-in-ring complex. Ministerio de Economía y Competitividad; CTQ-201341097-P Xunta de Galicia; EM2014/056 |
| Databáze: | OpenAIRE |
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