Rapid formation of diphenylmethyl ethers and thioethers using microwave irradiation and protic ionic liquids

Autor:	Nolene Byrne, Jennifer S. Squire, Bronwyn Fox, Simren K. Khosa, Cassandra L. Fleming, Frederick M. Pfeffer, Linden Servinis, Jarrad M. Altimari, Megan Thornton, Joshua P. Delaney, Matthew P. Wride, Trent D. Ashton, Mark D. Johnstone, Luke C. Henderson, Shane M. Hickey, Benjamin M. Long
Přispěvatelé:	Altimari, Jarrad M, Delaney, Joshua P, Servinis, Linden, Squire, Jennifer S, Thornton, Megan T, Khosa, Simren K, Long, Benjamin M, Johnstone, Mark D, Fleming, Cassandra L, Pfeffer, Frederick M, Hickey, Shane M, Wride, Matthew P, Ashton, Trent D, Fox, Bronwyn L, Byrne, Nolene, Henderson, Luke C
Rok vydání:	2012
Předmět:	Chemistry Organic Chemistry Inorganic chemistry Ether Biochemistry ether thioether law.invention Catalysis chemistry.chemical_compound Thioether law Drug Discovery Microwave irradiation Ionic liquid Organic chemistry diphenylmethyl ether microwave irradiation Filtration protic ionic liquid
Zdroj:	Tetrahedron Letters. 53:2035-2039
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2012.02.011
Popis:	Using microwave irradiation and protic ionic liquids (pIL) as co-solvent and catalyst for the synthesis of several diphenylmethyl ethers was achieved. The desired ethers were isolated simply by filtration through a silica plug to remove the pIL and proceeded in high yields (60-98%). These reactions were extremely rapid (10-30 min) and occurred under mild conditions (80 °C). This protocol was also successfully applied to the synthesis of thioethers. Refereed/Peer-reviewed
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a703fb89eda97387fac78bedcee7fb3b https://doi.org/10.1016/j.tetlet.2012.02.011 Zobrazit plný text záznamu Full Text from ScienceDirect