Total Regioselective Control of Tartaric Acid

Autor:	Ana I. Fernández-Llamazares, Jan Spengler, Javier Ruiz-Rodríguez, Fernando Albericio, Klaus Burger
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Chemistry Organic Chemistry Molecular Conformation Tartaric acid Organic chemistry Regioselectivity Stereoisomerism Tartrate Derivatization Tartrates Chemical synthesis
Zdroj:	The Journal of Organic Chemistry. 75:5746-5749
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo101001s
Popis:	An efficient strategy to synthesize tartaric acid building blocks for totally regioselective transformations or derivatizations was disclosed. Starting from l-tartaric acid or l-dimethyl tartrate, respectively, we obtained type I and II building blocks with orthogonal sets of protecing groups (4-8 steps, 38-56% overall yield).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a6fe210fe93b8710af0455d91f31b813 https://doi.org/10.1021/jo101001s Zobrazit plný text záznamu