Coordination chemistry of titanium and zinc in Ti(1−x)Zn2xO2 (0 ≤ x ≤ 1) ultrathin films grown by DC reactive magnetron sputtering
| Autor: | Olga Sánchez, Ramon Escobar Galindo, Ricardo Torres, Miriam Yuste, Ignacio A. Jiménez, Ignacio Caretti |
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| Přispěvatelé: | Universidad de Sevilla. Departamento de Física Aplicada I, Ministerio de Ciencia e Innovación (MICIN). España |
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
010302 applied physics
chemistry.chemical_classification Reactive magnetron Materials science General Chemical Engineering Inorganic chemistry Oxide Analytical chemistry chemistry.chemical_element 02 engineering and technology General Chemistry Zinc 021001 nanoscience & nanotechnology 01 natural sciences XANES Coordination complex chemistry.chemical_compound chemistry Sputtering 0103 physical sciences 0210 nano-technology Stoichiometry Titanium |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname |
| Popis: | XANES and RBS were used to explore the structural phase and composition transitions of ultrathin films with Ti (1-x)Zn 2xO 2 stoichiometries, from very low (∼0.5 at.%) to high (∼25 at.%) titanium content. In this way, the coordination chemistry of Ti 4+ and Zn 2+ cations was examined for a wide range of oxide compositions. © 2012 The Royal Society of Chemistry. The research leading to these results has received funding from the European Community’s Seventh Framework Programme (FP7/2007–2013) under grant agreement n.226716. This work has been partially financed by the Spanish MICINN through project Consolider FUNCOAT CSD2008-0023, and project MOCASIN MAT2010-21070-C02-02. I. Caretti acknowledges support from CSIC through a JAEDoc fellowship. R. Escobar Galindo would like to thank the MCINN for the financial support within the Ramón y Cajal programme (RyC2007-0026). |
| Databáze: | OpenAIRE |
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