Vibrational Spectrum of HMX at CO2 Laser Wavelengths: A Combined DRIFT and LPAS Study
| Autor: | Adriana Puiu, Gianfranco Giubileo, S. Nunziante Cesaro |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Diffuse reflectance infrared fourier transform
Article Subject Chemistry Resolution (electron density) Analytical chemistry Laser law.invention lcsh:Chemistry Wavelength lcsh:QD1-999 law lcsh:QC350-467 Emission spectrum Absorption (electromagnetic radiation) Photoacoustic spectroscopy lcsh:Optics. Light Line (formation) |
| Zdroj: | International Journal of Spectroscopy, Vol 2012 (2012) |
| ISSN: | 1687-9457 1687-9449 |
| Popis: | The vibrational spectrum of solid standard HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) was investigated. Two spectroscopic techniques were adopted for their different sensitivity and resolution. A preliminary survey of the absorption bands of the compound was performed in the 8000–400 cm−1 spectral range by employing the diffuse reflectance infrared Fourier transform (DRIFT) technique at room temperature. The high-resolution line spectrum of HMX was obtained in the 9.2–10.8 μm spectral range by laser photoacoustic spectroscopy (LPAS) method, using a line tuneable 10 W stabilised cw CO2 laser light source. By comparing the data collected with the two techniques in the common frequency range, a very good agreement was observed. |
| Databáze: | OpenAIRE |
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