Thiocyanatoarylation of Methyl Vinyl Ketone under Meerwein Conditions for the Synthesis of 2-Aminothiazole-Based Heterocyclic Systems
Autor: | Yurii V. Ostapiuk, Oksana V. Barabash, Mary Y. Ostapiuk, Evgeny Goreshnik, Mykola D. Obushak, Andreas Schmidt |
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Rok vydání: | 2022 |
Předmět: | |
Zdroj: | Organic letters. 24(25) |
ISSN: | 1523-7052 |
Popis: | 4-Aryl-3-thiocyanatobutan-2-ones were prepared by Meerwein reactions from methyl vinyl ketone and aryldiazonium salts under copper(II) catalysis in 35-75% yields. α-Thiocyanato ketones regioselectively react with 1-methyl-3-aminopyrazole forming |
Databáze: | OpenAIRE |
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