A novel tri-unsaturated highly branched isoprenoid (HBI) alkene from the marine diatom Navicula salinicola

Autor:	Evgeniy Gusev, Simin Gao, Simon T. Belt, Thomas Mock, Nikolai Pedentchouk, Maxim Kulikovskiy, Nataliya Shkurina, Lukas Smik
Rok vydání:	2020
Předmět:	chemistry.chemical_classification biology Chemistry Stereochemistry Alkene Marine diatom biology.organism_classification Navicula salinicola Terpenoid Diatom Geochemistry and Petrology Navicula Conjugated diene Haslea ostrearia
Zdroj:	Organic Geochemistry. 146:104050
ISSN:	0146-6380
DOI:	10.1016/j.orggeochem.2020.104050
Popis:	A novel tri-unsaturated C25 highly branched isoprenoid (HBI) alkene has been identified in a laboratory culture of the diatom Navicula salinicola and its structure determined using a combination of NMR spectroscopy and gas chromatography–mass spectrometry (GC–MS). This represents the first report of a C25 HBI in a marine diatom from the Navicula genus, although a different tri-unsaturated C25 HBI has been reported previously in the freshwater species N. sclesvicensis and unspecified HBIs have been identified in the brackish N. phyllepta. The newly characterised HBI contains a relatively unusual conjugated diene sub-unit, a structural feature only previously reported in some HBIs biosynthesised by a further marine diatom, Haslea ostrearia.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a60e45e2d47b4339cc66afe44f48a2ff https://doi.org/10.1016/j.orggeochem.2020.104050 Zobrazit plný text záznamu Full Text from ScienceDirect