Thermo-sensitive and environmental friendly diblock copolymers obtained via ATRP/ROP combination
| Autor: | Mustapha Raihane, Hicham Qayouh, Cécile Nouvel, Jérôme Babin, Jean-Luc Six, Mohammed Lahcini |
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| Přispěvatelé: | Laboratoire de Chimie Physique Macromoléculaire (LCPM), Centre National de la Recherche Scientifique (CNRS)-Université de Lorraine (UL), Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), Université Cadi Ayyad [Marrakech] (UCA), Institut de Chimie du CNRS (INC)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Amphiphilic copolymers
Materials science Atom-transfer radical-polymerization [CHIM.ORGA]Chemical Sciences/Organic chemistry Diethylene glycol Ether Methacrylate chemistry.chemical_compound Thermo-responsive polymers [CHIM.POLY]Chemical Sciences/Polymers chemistry Polymerization Polymer chemistry Auto-organization Copolymer Biodegradable Bifunctional Agronomy and Crop Science Trifluoromethanesulfonate ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Industrial Crops and Products Industrial Crops and Products, Elsevier, 2015, 72, pp.60-68. ⟨10.1016/j.indcrop.2015.01.047⟩ Industrial Crops and Products, Elsevier, 2015, 72 (SI), pp.60-68. ⟨10.1016/j.indcrop.2015.01.047⟩ |
| ISSN: | 0926-6690 |
| DOI: | 10.1016/j.indcrop.2015.01.047⟩ |
| Popis: | International Conference on Bio-Based Materials and Composites (ICBMC 14), Montreal, CANADA, MAY 13-16, 2014; International audience; Atom Transfer Radical Polymerization (ATRP) and Ring-Opening Polymerization (ROP) were combined to synthesize diblock environmental friendly poly(E-caprolactone)-block-poly(methyl ether diethylene glycol methacrylate) (PCL-b-PMEO(2)MA) through a sequential two-step strategy. These PCL-b-PMEO2MA copolymers were produced using 2-hydroxyethyl-2-bromoisobutyrate as bifunctional initiator. In the first step, E-caprolactone was initiated by the hydroxyl group of this particular initiator. Tin octoate, zinc triflate and bismuth triflate were tested as non-toxic catalysts to obtain alpha-bromide-omega-hydroxy bifunctional PCL macroinitiator. Secondly, the controlled ATRP of MEO(2)MA was tuned from the same bifunctional initiator. Finally, PCL-b-PMEO(2)MA were produced by carrying out ATRP of MEO(2)MA from PCL macroinitiator. Preliminary data on self-assembly of such thermo-sensitive PCL-b-PMEO(2)MA in aqueous phase are given. |
| Databáze: | OpenAIRE |
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