Structure, Dynamics, and Reactivity for Light Alkane Oxidation of Fe(II) Sites Situated in the Nodes of a Metal-Organic Framework

Autor:	Michelle L. Beauvais, Adam S. Hoffman, Connie C. Lu, Melike Babucci, Bruce C. Gates, Simon R. Bare, Jenny G. Vitillo, Karena W. Chapman, Alexey Boubnov, Matthew C. Simons, Christopher J. Cramer, Aditya Bhan, Laura Gagliardi, Zhihengyu Chen
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	Alkane chemistry.chemical_classification General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Colloid and Surface Chemistry chemistry Chemical engineering Situated Reactivity (chemistry) Metal-organic framework Porosity
Popis:	Metal organic frameworks (MOFs), with their crystalline, porous structures, can be synthesized to incorporate a wide range of catalytically active metals in tailored surroundings. These materials have potential as catalysts for conversion of light alkanes, feedstocks available in large quantities from shale gas that are changing the economics of manufacturing commodity chemicals. Mononuclear high-spin (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a608befec53d848c97858f512e2ad5fe http://hdl.handle.net/11383/2103582 Zobrazit plný text záznamu