One pot synthesis of aminohydroxylated triglycerides under aqueous biphasic conditions
| Autor: | Théodore Vanbesien, Eric Monflier, Kévin Cousin, Frédéric Hapiot |
|---|---|
| Přispěvatelé: | Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, UCCS Équipe Catalyse Supramoléculaire, Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille-Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2019 |
| Předmět: |
Aqueous solution
[CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Process Chemistry and Technology One-pot synthesis General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry [CHIM]Chemical Sciences Organic chemistry Hydroxymethyl Triolein Chemoselectivity ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Catalysis Communications Catalysis Communications, Elsevier, 2019, 125, pp.37-42. ⟨10.1016/j.catcom.2019.03.018⟩ Catalysis Communications, 2019, 125, pp.37-42. ⟨10.1016/j.catcom.2019.03.018⟩ |
| ISSN: | 1566-7367 |
| Popis: | Herein is reported the one pot cascade hydroaminomethylation (HAM)/hydrohydroxymethylation (HHM) of triolein (T) using hydroformylating and hydrogenating Rh-catalysts stabilized by both phosphanes and amines under aqueous biphasic conditions. While T are mainly functionalized by N,N′-dialkylaminomethyl groups in organic solvents, they are predominantly functionalized by hydroxymethyl groups under aqueous biphasic conditions. The change in chemoselectivity is a consequence of both the displacement of the enamine-aldehyde equilibrium upon addition of water, and the partition of Rh-catalysts between the organic and the aqueous phases. |
| Databáze: | OpenAIRE |
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