Tristhienylphenylamine – extended dithiafulvene hybrids as bifunctional electroactive species

Autor: Emilie Ripaud, Nicolas Cocherel, Jean Roncali, Thomas Cauchy, Pierre Frère, Philippe Leriche
Přispěvatelé: MOLTECH-Anjou, Université d'Angers (UA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Rok vydání: 2011
Předmět:
Zdroj: Organic and Biomolecular Chemistry
Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2011, 9 (4), pp.1034-1040. ⟨10.1039/c0ob00471e⟩
ISSN: 1477-0539
1477-0520
DOI: 10.1039/c0ob00471e
Popis: Extended hybrid conjugated systems based on a trithienylphenylamine core with 1, 2 and 3 peripheral dithiafulvenyl units have been synthesized and studied by cyclic voltammetry and UV-Vis. absorption spectroscopy. Theoretical calculations have also been undergone. The behaviour of these derivatives which depends on the number of dithiafulvene moieties grafted of the central core is cleared up. One polymer, obtained from derivative 3 presents polyelectrochromic properties.
Databáze: OpenAIRE