β-Alkyl Elimination: Fundamental Principles and Some Applications
| Autor: | Matthew E. O'Reilly, Saikat Dutta, Adam S. Veige |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Depolymerization General Chemistry 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Elimination reaction Organic reaction chemistry Polymerization Hydrogenolysis Moiety Organic chemistry Alkyl Group 2 organometallic chemistry |
| Zdroj: | Chemical Reviews. 116:8105-8145 |
| ISSN: | 1520-6890 0009-2665 |
| DOI: | 10.1021/acs.chemrev.6b00054 |
| Popis: | This review describes organometallic compounds and materials that are capable of mediating a rarely encountered but fundamentally important reaction: β-alkyl elimination at the metal-Cα-Cβ-R moiety, in which an alkyl group attached to the Cβ atom is transferred to the metal or to a coordinated substrate. The objectives of this review are to provide a cohesive fundamental understanding of β-alkyl-elimination reactions and to highlight its applications in olefin polymerization, alkane hydrogenolysis, depolymerization of branched polymers, ring-opening polymerization of cycloalkanes, and other useful organic reactions. To provide a coherent understanding of the β-alkyl elimination reaction, special attention is given to conditions and strategies used to facilitate β-alkyl-elimination/transfer events in metal-catalyzed olefin polymerization, which provide the well-studied examples. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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