Crystal structure of 3-amino-5,5-dimethyl-2-[(E)-2-nitroethenyl]cyclohex-2-en-1-one
| Autor: | Anatoly Mishnev, Brigita Vigante, Andrejs Pelss, Dmitrijs Stepanovs |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: |
nitroacetaldehyde
crystal structure Hydrogen bond Chemistry nitrodienamines nitroacetaldehyde General Chemistry Crystal structure nitrodienamines Condensed Matter Physics Bioinformatics Research Communications lcsh:Chemistry Crystal Crystallography lcsh:QD1-999 hydrogen bonds Nitro Knoevenagel-type condensation General Materials Science |
| Zdroj: | Acta Crystallographica Section E: Structure Reports Acta Crystallographica Section E, Vol 70, Iss 11, Pp 379-381 (2014) |
| ISSN: | 1600-5368 |
| Popis: | The asymmetric unit of the title compound contains two independent molecules with similar conformations, the cyclohexene rings adopting the same envelope conformation. In the crystal, adjacent molecules are connected via N—H⋯O hydrogen bonds and weak C—H⋯O interactions, forming supramolecular layers parallel to (01). The asymmetric unit of the title compound, C10H14N2O3, contains two independent molecules with similar conformations. In the both molecules, the cyclohexene rings adopt the same envelope conformation with the flap C atoms lying 0.658 (3) and 0.668 (3) Å from the mean planes formed by the remaining atoms. In the crystal, adjacent molecules are connected via N—H⋯O hydrogen bonds and weak C—H⋯O interactions, forming supramolecular layers parallel to (-101). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|