Interpenetrating inclusion lattices: Comparison of the Β-hydroquinone and ellipsoidal clathrate structures
| Autor: | Roger Bishop, Don C. Craig, Alison T. Ung, Ian G. Dance, Marcia L. Scudder |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Hydroquinone
Solid-state physics Hydrogen bond Chemistry Superlattice Clathrate hydrate Clathrate compound law.invention Inorganic Chemistry chemistry.chemical_compound Crystallography law Materials Chemistry Inorganic & Nuclear Chemistry Physical and Theoretical Chemistry Crystallization Acetonitrile |
| Zdroj: | Journal of Structural Chemistry. 40:663-671 |
| ISSN: | 1573-8779 0022-4766 |
| Popis: | Crystallization of 2,7-dimethyltricyclo[4.3.1.13,8]undecane-syn-2,syn-7-diol 2 from acetonitrile or dichloromethane yields the compounds (2)4· (guest) in space group I41/acd which are further examples of the ellipsoidal clathrate structure. Both enantiomers of 2 are linked through (O-H)4 cycles of hydrogen bonds to form a three-dimensional sublattice. Two inversion related sublattices interpenetrate thereby generating a superlattice with guest-occupied voids situated between the two individual sublattices. The two X-ray structures are compared and contrasted with that of Powell's (hydroquinone)3· (SO2) clathrate compound. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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