NIR vibrational overtone spectra of toluidines—evidence for steric and electronic effects in o-toluidine
| Autor: | K.P.R. Nair, Sadasivan Shaji, Shibu M. Eappen, T.M.A Rasheed |
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| Rok vydání: | 2004 |
| Předmět: |
Steric effects
Spectroscopy Near-Infrared Toluidines Absorption spectroscopy Chemistry Overtone Photochemistry Atomic and Molecular Physics and Optics Analytical Chemistry Ab initio quantum chemistry methods Electronic effect Physics::Chemical Physics Laser-induced fluorescence Spectroscopy Instrumentation |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 60:2275-2281 |
| ISSN: | 1386-1425 |
| DOI: | 10.1016/j.saa.2003.11.026 |
| Popis: | The near infrared vibrational overtone absorption spectra of liquid phase toluidines are reported. The analysis of the observed CH and NH local mode mechanical frequency values shows that there exists steric and electronic interaction between the amino and methyl groups in o-toluidine. This observation supports the conclusions drawn from structural studies of toluidines by resonance two-photon ionization (R2PI) spectroscopy, ab initio calculations and laser induced fluorescence studies reported earlier. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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