Chemoenzymatic synthesis of the carbasugars carba-β-l-galactopyranose, carba-β-l-talopyranose and carba-α-l-talopyranose from methyl benzoate
| Autor: | Nigel I. Bowers, Colin O'Dowd, Christopher C. R. Allen, Paul J. Stevenson, Narain D. Sharma, John F. Malone, Gerard B. Coen, Derek R. Boyd |
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| Rok vydání: | 2010 |
| Předmět: |
Magnetic Resonance Spectroscopy
Pseudomonas putida Chemistry Stereochemistry Metabolite Organic Chemistry Alpha (ethology) Carbasugars Stereoisomerism Nuclear magnetic resonance spectroscopy Methyl benzoate Crystallography X-Ray Benzoates Biochemistry chemistry.chemical_compound Biocatalysis Oxygenases Physical and Theoretical Chemistry Beta (finance) |
| Zdroj: | Organic & Biomolecular Chemistry. 8:1415 |
| ISSN: | 1477-0539 1477-0520 |
| DOI: | 10.1039/b921545j |
| Popis: | The cis-dihydrodiol metabolite from methyl benzoate has been used as a synthetic precursor of carba-beta-L-galactopyranose, carba-beta-L-talopyranose and carba-alpha-L-talopyranose. The structures and absolute configurations of these carbasugars were determined by a combination of NMR spectroscopy, stereochemical correlation and X-ray crystallography. |
| Databáze: | OpenAIRE |
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