Cyclic dialkylindium amides: new structural information and ultra-purification using inorganic and inorgano–organic layered materials
| Autor: | Franco Benetollo, Iryna A. Grafova, Riccardo Vivani, Andrei V. Grafov |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) Chemistry Organic Chemistry Inorganic chemistry chemistry.chemical_element Sorption Crystal structure Biochemistry Indium Ion Inorganic Chemistry Metal visual_art Materials Chemistry visual_art.visual_art_medium Molecule layer materials structure Physical and Theoretical Chemistry nitrogen ligands Group 2 organometallic chemistry |
| Zdroj: | Journal of organometallic chemistry 689 (2004): 3000–3008. info:cnr-pdr/source/autori:I. Grafova 1, R. Vivani 2, A. Grafov 3, F. Benetollo 4/titolo:Cyclic dialkylindium amides: new structural information and ultra-purification using inorganic and inorgano-organic layered materials/doi:/rivista:Journal of organometallic chemistry (Print)/anno:2004/pagina_da:3000/pagina_a:3008/intervallo_pagine:3000–3008/volume:689 |
| Popis: | New data on some cyclic dimethyl- and diethylindium-amides were obtained. X-ray structure of pyrrolidinodimethylindium was determined. The molecule is centrosymmetric with square–planar In 2 N 2 base and distorted tetrahedral metal environment similar to that of known dialkylindium amides, the cyclic amido-ligands are present in an envelope conformation. A novel material- and energy-saving procedure for sorption ultra-purification of highly sensitive organometallic compounds in absolute non-polar media was developed. Advanced inorganic and inorgano–organic crystalline layered materials possessing enhanced affinity towards selected ions or molecules were applied for the sorption treatment. |
| Databáze: | OpenAIRE |
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