Synthesis and co-polymerization of an unsaturated 1,5-anhydro-D-fructose derivative
| Autor: | Anke Glümer, Olaf Deppe, Shukun Yu, Klaus Buchholz |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Magnetic Resonance Spectroscopy Spectrophotometry Infrared Organic Chemistry D fructose Radical polymerization Regioselectivity General Medicine Polymer Fructose Biochemistry Analytical Chemistry chemistry.chemical_compound chemistry Polymerization Acetylation Yield (chemistry) Polymer chemistry Carbohydrate Conformation Organic chemistry Derivative (chemistry) |
| Zdroj: | Carbohydrate research. 339(12) |
| ISSN: | 0008-6215 |
| Popis: | An unsaturated derivative, 3,6-di-O-acetyl-1,5-anhydro-4-deoxy-D-glycero-hex-3-enopyranos-2-ulose (3), was obtained via regioselective elimination and acetylation of monohydrated 1,5-anhydro-D-fructose (1) in a single step reaction. High yield (80%) was achieved without any dimeric by-products. Its co-polymerization to saccharide polymers was investigated with different commercial vinyl co-monomers. Co-polymers were obtained and characterized. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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