Production of Au/phosphonium polymer nanoparticles
| Autor: | Pelin Sungur, Tarik Eren, Ali Bayır, N. Ceren Süer, İlayda Acaroğlu Degitz |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Organic Chemistry Cationic polymerization General Physics and Astronomy Nanoparticle 02 engineering and technology Polymer ROMP 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound X-ray photoelectron spectroscopy chemistry Colloidal gold Polymer chemistry Materials Chemistry Surface modification Phosphonium 0210 nano-technology |
| Zdroj: | European Polymer Journal. 156:110599 |
| ISSN: | 0014-3057 |
| DOI: | 10.1016/j.eurpolymj.2021.110599 |
| Popis: | The introduction of cationic groups onto the surface of gold nanoparticles (GNPs) is a valuable synthetic technique with many applications. This study reports the synthesis of the functionalization of GNPs with phosphonium groups presented in the ring opening metathesis (ROMP)-type polymer backbone. The formation of nanoparticles was revealed with UV-spectroscopy and Transmission Electron Microscopy (TEM). The presence of polyphosphonium ligand on the surface of the GNPs was confirmed by XPS and 31P NMR spectroscopy. Higher molecular weight polymer-GNPs exhibited better stability in the ambient conditions than the phosphonium polymers which possessed lower molecular weights. Phosphonium-based polymers can act, simultaneously, as reducing and stabilizing agents for the gold nanoparticles. |
| Databáze: | OpenAIRE |
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